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jueves, 13 de junio de 2013

The importance of magnesium and iron

The importance of magnesium and iron.

Nota bene: this text has been translated from Spanish to English mainly by Google Translator, so, please excuse any spelling or grammar errors.

These metals are very important chemical elements.

Magnesium forms part of a molecule called chlorophyll (a green pigment).

Iron forms part of a molecule called hemoglobin (which is a protein, a metalloprotein, in fact).

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Magnesium is an alkaline earth metal.

Symbol: Mg (from the Latin word magnesium).

Atomic number: 12.

It has 12 protons and usually 12 neutrons in its nucleus, but there are isotopes that have 13 or 14 neutrons; and it has 12 electrons orbiting the nucleus: two in its first energy level or K shell, eight in its second energy level or L shell, and two in its third energy level or M shell.

Relative atomic weight: 24.305.

Valence: +2.

It is located in group 2: in the second column (below the chemical element called Beryllium, Be), and in the third row or line (to the right side of sodium, Na) in the Periodic Table of the Chemical Elements of Russian chemist Dmitri Mendeleev (1834 -1907).

         It is not found free in nature, but forming compounds such as magnesium chloride, MgCl2.

         It is the sixth, seventh or eighth most abundant element in the Earth's crust (there are discrepancies), representing about 2 percent of the Earth's crust, and it is the third most abundant chemical element dissolved in seawater.

         It is usually obtained from magnesium chloride, MgCl2, which is found dissolved in the seawater.

         Magnesium ion is essential for all living cells.

         In industry, magnesium is used as an alloying element.

         Magnesium hydroxide, Mg(OH)2, or milk of magnesia is used in medicine, for example, as an antacid.

         There are ordinary people who use it as well, without evidence of its effectiveness:

         1. To mitigate the burns caused by the sun after being at the beach, the desert, very hot areas, et cetera
         2. As a deodorant, especially on sensitive skin.
         3. To soothe burnings caused by irritation of the skin (burns, allergies...).
         4. In baby's bottom to soothe diaper rash.
         5. Diluted in water, milk of magnesia is often used in the oily areas of the skin of young and adult people (some women apply it before moisturizer; others, after moisturizer).

         Magnesium chloride, MgCl2, is used in medicine, but also in the manufacture of paper, textiles, concrete, and as an anti-freezing agent: magnesium chloride is sprayed on dry pavements of airport runways before the snow falls, or on wet pavements before the water reaches freezing temperatures in the winter.

         Magnesium citrate is used as a laxative.

         Magnesium sulfate, MgSO4, as such, is used almost exclusively in the industry as a drying agent, but hydrated: MgSO4 • 7H2O, or Epsom salt, or English salt, has a broader use in medicine, for example in bath salts.
         It is used in agriculture and gardening to correct magnesium deficiency in soil.

         Magnesium carbonate, MgCO3, is used in powder form by gymnasts and weightlifters to enhance their grip at the bars, still rings, pommel horses, et cetera.
         In high-level escalation is used to improve the grip of the hands to the rock. Climbers carry it in a bag hanging from their belts.
         (In contrast, violinists, and baseball pitchers use rosin in powder form ––a resinous substance, Pix graeca, obtained from turpentine of pines, firs, larches, or terebinths.)

Magnesium (Mg) forms part of the chlorophyll molecule, a vegetal substance essential to life, which is in the chloroplasts (organelles of plant cells).

Chlorophyll is found in cyanobacteriae, algae and in all organisms that have chloroplasts in their cells, that is, in plants.

The pigment chlorophyll is essential in photosynthesis, an important biochemical process that allows plants to absorb energy from light.

         The chlorophyll molecule has two parts: a porphyrin ring (one
tetrapyrrole, in this case), and a long chain known as phytol.

         Vegetal porphyrin has at its center a magnesium ion (Mg2+), surrounded by four nitrogen atoms, N, many atoms of hydrogen, H, and a few atoms of oxygen, O.

         In vertebrates, iron, Fe, occupies a position equivalent to the magnesium in the plants.

         Through their roots, terrestrial plants absorb water and minerals, including magnesium, from the soil; and mainly through their leaves, plants capture carbon dioxide, CO2 from the Earth's atmosphere, to form carbohydrates (molecules as glucose, cellulose, id est, compounds of carbon, C, hydrogen, H, and oxygen, O) and release oxygen, O2, to the atmosphere.

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Iron is a transitional metal.

Symbol: Fe (from the Latin word ferrum).

Atomic number: 26.

It has 26 protons and usually 28 or 30 neutrons in its nucleus. There are other stable isotopes which have 31 or 32 neutrons; and it has 26 electrons orbiting the nucleus: two in its first energy level or K shell, eight in its second energy level or L shell, fourteen in its third energy level or M shell, and two in its fourth energy level or N shell.

Relative atomic weight: 55.85, or 55,847, or 55,845, or 55.6 (there are variations or discrepancies).

Valences: +2, +3.

It is located in the group 8, at the top of the eighth column (above ruthenium, Ru), and in the fourth row or line (to the right of Manganese, Mn) in the Periodic Table of the Chemical Elements of Russian chemist Dmitri Mendeleev (1834-1907).
         Iron, Fe, is rarely found free in nature. It is the fourth most abundant element in the earth's crust, and among the metals, only aluminum, Al, is more abundant. It forms part of many minerals, including a lot of oxides. In order to obtain iron in an elemental state, the iron oxides are reduced with carbon and then are refined to remove impurities.

         Nuclear fusion in massive (giant) stars is definitively concluded when in their centers there is only iron. So, in the early stages of a star's life (either very massive, massive, medium, or "small"), hydrogen (“stuff”) is going fusing to form helium: four nuclei of hydrogen, H, form a nucleus of helium, He.
         Then when all the hydrogen in the center of the star has been transformed into helium, other nuclear reactions can occur. If the temperature in the center of the star reaches 200 million degrees, helium nuclei fuse together and generate carbon and oxygen, if the temperature further increases, it can occur formation of neon, Ne, sodium, Na, and magnesium, Mg.
         If the core temperature reaches about 3,000 million degrees, it can occur formation of all atomic nuclei which are not heavier than the iron. The not very massive stars can not produce iron, as the temperature of their respective centers never becomes as high as the center of very massive stars.

         The Earth's core consists mainly of iron, Fe, and nickel, Ni.
Iron is the most widely used hard metal, it constitutes about 95 percent of world production of metal.
         In industry, iron is used for making steel, when combined with carbon, C (obtained from coke, coal), in a proportion equal to or less than 2 percent of carbon if the iron-carbon alloy has more carbon generally it is not called steel but casting (with carbon in an amount from 2.1 or 2.14 to 6.67 percent).
         The steel is used in vehicles, boats, beams, girders, joists, columns, to build houses and buildings structures, railroad tracks.
         Also produce large amounts of cast iron and wrought iron, barriers, gates, fences, garden furniture...
         Iron is used to make magnets, inks, paper blueprints, pigments polishers, abrasives.

Iron is an essential part of blood cells called erythrocytes or red blood cells, as it is an indispensable element of the complex protein molecule called hemoglobin, which is responsible for transporting oxygen (O2) to all body tissues of humans and vertebrate animals, and some invertebrates.

         Iron exists only in small amounts in living beings, however, its role is vital in the growth and survival, and it is essential not only to obtain adequate tissue oxygenation, but also for the metabolism of most of the cells.

         Hemoglobin is a conjugate protein or heteroprotein, comprised of four polypeptide chains (globin), each of which binds a heme group.

A heme group consists of:
         (A) A succinyl-CoA* binding at amino acid glycine to form a pyrrole.
         *A combination of succinic acid and coenzyme A.
         (B) Four pyrrole groups together to integrate protoporphyrin IX.
         (C) Protoporphyrin IX binds a ferrous ion (Fe 2+) to form a heme group.

         A heme group has at its center a ferrous ion (Fe2+), surrounded by four nitrogen atoms, N, some CH radicals (carbon and hydrogen), two OH radicals (hydrogen and oxygen) and two oxygen atoms.

         In plants, magnesium occupies a position equivalent to iron in vertebrates.

         When hemoglobin carries oxygen, is called oxyhemoglobin or oxygenated hemoglobin, which travels “on board” of erythrocytes (red blood cells) of the arterial blood.

         When hemoglobin carries carbon dioxide (CO2), is called carbaminohemoglobin or carbohemoglobin, which travels “on board” of venous blood erythrocytes after gas exchange between these erythrocytes and tissues.

         Under different conditions, illnesses or diseases, congenital diseases, poisoning, stages of life (the fetal stage, for example), in humans there may be up to nine types of hemoglobin, but the most common or “natural ones most of the time”, are the two mentioned above.
         Erythrocytes or red blood cells are specialized cells. The red blood cells of mammals are anucleate when mature, meaning that they lack a cell nucleus. In contrast, the erythrocytes of other vertebrates have nuclei, the only known exceptions are salamanders of the Batrachoseps genus and fishes of the Maurolicus genus.

         Anemia is defined as a low hemoglobin concentration in the blood. It is not a disease but a symptom; one of its most common causes is iron deficiency.

         Its origin may be an insufficient intake of iron, or bleeding.

         Doctors often prescribe oral or injected iron to anemic individuals.

         Also doctors can prescribe iron, in appropriate doses and through appropriate channels, to pregnant women (in addition to calcium, folic acid, et cetera).

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In “slaughterhouses” of some Mexican and Spanish bullrings, certain people (women and men alike) drink bull’s blood after a bullfight or corrida; previously they often pick up the blood in disposable glasses after an employee has cut one or more blood vessels of the hung bull, which has been killed previously by the bullfighter or matador.

Also, in Mexico, some people drink bull’s blood during several traditional religious feasts; for example:

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